1.1 This test method covers the determination of dissolved, total-recoverable, or total elements in drinking water, surface water, domestic, or industrial wastewaters. ,
1.2 It is the user's responsibility to ensure the validity of the test method for waters of untested matrices.
1.3 Table 1 lists elements for which this test method applies, with recommended wavelengths and typical estimated instrumental detection limits using conventional pneumatic nebulization. Actual working detection limits are sample dependent and as the sample matrix varies, these detection limits may also vary. In time, other elements may be added as more information becomes available and as required.
1.4 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.5 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. For specific hazard statements, see Note 2 and Section 9.
TABLE 1 Suggested Wavelengths and Estimated
Detection Limits
| Element | Wavelength, nmA | Estimated detection limit,μ g/LB |
|---|---|---|
| Aluminum | 308.215 | 45 |
| Arsenic | 193.696 | 53 |
| Antimony | 206.833 | 32 |
| Beryllium | 313.042 | 0.3 |
| Boron | 249.773 | 5 |
| Cadmium | 226.502 | 4 |
| Chromium | 267.716 | 7 |
| Cobalt | 228.616 | 7 |
| Copper | 324.754 | 6 |
| Iron | 259.940 | 7 |
| Lead | 220.353 | 42 |
| Magnesium | 279.079 | 30 |
| Manganese | 257.610 | 2 |
| Molybdenum | 202.030 | 8 |
| Nickel | 231.604 | 15 |
| Selenium | 196.026 | 75 |
| Silver | 328.068 | 7 |
| Thallium | 190.864 | 40 |
| Vanadium | 292.402 | 8 |
| Zinc | 213.856 | 2 |
A The wavelengths listed are recommended because of their sensitivity and overall acceptance. Other wavelengths may be substituted if they can provide the needed sensitivity and are treated with the same corrective techniques for spectral interference (see 6.1.1).
B The estimated detection limits as shown are taken from Winge, Fassel, et al. They are given as a guide for approximate detection limits for the listed wavelengths. The actual test method instrumental detection limits are sample-dependent and may vary as the sample matrix varies (see 3.1.3).
Product Details
- Published:
- 03/01/2012
- Number of Pages:
- 9
- File Size:
- 1 file , 110 KB
- Redline File Size:
- 2 files , 220 KB
