1.1 This test method covers the determination of total carbon (TC), inorganic carbon (IC), and total organic carbon (TOC) in water in the range from 0.5 to 30 mg/L of carbon. Higher levels may be determined by sample dilution. The test method utilizes ultraviolet-persulfate oxidation of organic carbon, coupled with a CO2 selective membrane to recover the CO2 into deionized water. The change in conductivity of the deionized water is measured and related to carbon concentration in the oxidized sample. Inorganic carbon is determined in a similar manner without the requirement for oxidation. In both cases, the sample is acidified to facilitate CO2 recovery through the membrane. The relationship between the conductivity measurement and carbon concentration is described by a set of chemometric equations for the chemical equilibrium of CO2, HCO3−, H+, and the relationship between the ionic concentrations and the conductivity. The chemometric model includes the temperature dependence of the equilibrium constants and the specific conductances.
Product Details
- Published:
- 02/01/2017
- Number of Pages:
- 7
- File Size:
- 1 file , 180 KB
